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21.
Yu. N. Ovchinnikov I. A. Luk’yanchuk 《Journal of Experimental and Theoretical Physics》2002,94(1):203-215
The problem of the effective conductivity and the distributions of a field and currents is analyzed in a regular two-component system composed of regular triangles. An efficient solution method is developed that admits a generalization to multicomponent systems. 相似文献
22.
A new class of nodal topological excitations in a 2D Heisenberg model is studied. The solutions correspond to a nodal singular point of the gradient field of the azimuthal angle. An analytical solution is found for the isotropic case. The effect of in-plane exchange anisotropy is studied numerically. This results in solutions which are analogues of the conventional out-of-plane solitons in 2D magnets. 相似文献
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Topochemical investigations of peptide systems 总被引:4,自引:0,他引:4
M M Shemyakin Y A Ovchinnikov V T Ivanov 《Angewandte Chemie (International ed. in English)》1969,8(7):492-499
The basic principles of the topochemical approach to the investigation of the structure-function relation in peptide systems are formulated. This approach makes use of the new possibility of transforming natural peptides, consisting in the modification of the molecule as a whole and utilization of the resultant analogs to elucidate the boundaries of the stereoelectronic complementarity of the biologically active peptide to the corresponding receptor. In particular, on the example of depsipeptide antibiotics and their topochemical analogs the fruitfulness of using such compounds as tools in elucidating the physicochemical basis of functioning of biological membranes is shown. The topochemical principle has also been applied in preparing specific competitive inhibitors of proteolytic enzymes, whose study may shed light on the nature of the forces binding the substrate to the contact site of the corresponding enzyme. 相似文献
25.
A. A. Korlyukov K. A. Lyssenko M. Yu. Antipin A. G. Shipov O. A. Zamyshlyaeva E. P. Kramarova Vad. V. Negrebetsky S. A. Pogozhikh Yu. E. Ovchinnikov Yu. I. Baukov 《Russian Chemical Bulletin》2004,53(9):1924-1931
The reaction of 4-(2-hydroxybenzoyl)-2,2,6,6-tetramethyl-2,6-disilamorpholine with BF3Et2O afforded (O-B)-chelate 4-[2-(difluoroboroxy)benzoyl]-2,2,6,6-tetramethyl-2,6-disilamorpholine. Treatment of the latter with BF3Et2O or SOCl2 gave rise to products of the disilamorpholine ring opening, viz., (O-B) chelate 2-(difluoroboroxy)-N,N-bis(dimethylfluorosilylmethyl)benzamide or 2-(difluoroboroxy)-N, N-bis(dimethylchlorosilylmethyl)benzamide, respectively. The structures of the compounds synthesized were confirmed by X-ray diffraction analysis and 1H, 13C, and 29Si NMR spectroscopy. High-precision X-ray diffraction study and quantum-chemical calculations demonstrated that the coordination OSi bond is absent in the two last-mentioned compounds.Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1846–1853, September, 2004. 相似文献
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M. M. Shemyakin V. A. Puchkov N. S. Vul'fson V. N. Bochkarev Yu. A. Ovchinnikov A. A. Kryushkin V. T. Ivanov E. I. Vinogradova M. Yu. Feigina 《Russian Chemical Bulletin》1966,15(9):1483-1486
Conclusions The fragmentation of cyclodidepsipeptides during electron impact was investigated. The nature of the hydroxy and amino acid residues contained in the 2,5-diketomorpholines can be established on the basis of the mass spectra.For the preceding Communication, see [1].Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 1539–1543, September, 1966. 相似文献
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Heptakis(6-deoxy-6-guanidino)-β-cyclodextrin, prepared by one-step reaction of heptakis(6-amino-6-deoxy)-β-cyclodextrin with 1H-pyrozolecarboxamidine, binds ADP/ATP very tightly. 相似文献